Lessons learned from OECD CSNI ISP on small break loca :

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Additional info for Lessons learned from OECD CSNI ISP on small break loca : final report July 1996

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4 Biodegradability of Petroleum Hydrocarbons . . . . . . . . . . 1 Nonoxygenated Hydrocarbons . . . . . . . . . . . . . . . 2 Fully Oxygenated Hydrocarbons . . . . . . . . . . . . . . 5 Biodegradability of Halogenated Hydrocarbons . . . . . . . . . 1 Hydrolytic Dechlorination . . . . . . . . . . . . . . . . . 2 Oxidative Dehalogenation . . . . . . . . . . . . . . . . . 3 Reductive Dechlorination . . .

For a partly oxygenated ring, such as phenol, the monooxygenation leads directly to catechol. The unoxygenated ring can also be Ring monooxygenation 0 M + 2H+ + 2e· + 0 2 - do + H20 H epoxide benzene H H20 OOH OH +aO ~ H + 2H+ + 2e· catechol OH 0 + 2H+ + 2e·+ 0 2 - M phenol OH I OOH catechol Ring dloxygenations dihydrodiol toluene CH 3 OH~H OH Fig. 3. Examples of initial oxygenation steps for aromatic hydrocarbons 48 Bruce E. :::o ,,o H-C c-oH 11 H-C I 'c~c, 1 H OH Unsaturated hydroxy ketone carboxylate M and D indicate monooxygenation and dioxygenation reactions, respectively.

2 Model Solution . . . . . . . . . . . . . . . . . . . 3 Cosubstrate Effects . . . . . . . . . . . . . . . . . . . . 4 Abiotic Removals . . . . . . . . . . . . . . . . . . . . 4 Biodegradability of Petroleum Hydrocarbons . . . . . . . . . . 1 Nonoxygenated Hydrocarbons . . . . . . . . . . . . . . . 2 Fully Oxygenated Hydrocarbons . . . . . . . . . . . . . . 5 Biodegradability of Halogenated Hydrocarbons .

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